SHOWW WORK PLZZZ HELP

Iknow the answer to 13 is b and 14 is d. i just need to know why the correct answers are correct

Ammonium perchlorate nh4clo4 is the solid rocket fuel used by the u.s. space shuttle. it reacts with itself to produce nitrogen gas n2 , chlorine gas cl2 , oxygen gas o2 , water h2o , and a great deal of energy. what mass of nitrogen gas is produced by the reaction of 2.1g of ammonium perchlorate?

The comparison of the number of atoms in a copper coin the size of a penny with the number of people on earth is made to illustrate which of the following? a. that atoms are indivisible b. that atoms are very small c. that atoms are very large d. that in a copper penny, there is one atom for every person on earth