Cant figure out how to draw these graphs i really need help.

Argon is adiabatically compressed from an initial volume of 16 liters to a final volume of 2 liters. by what factor do the following quantities change? do they increase or decrease? (a) the rms speed (b) the thermal energy of the gas (c) the molar specific heat cv (d) the pressure

Some material consisting of a collection of microscopic objects is kept at a high temperature. a photon detector capable of detecting photon energies from infrared through ultraviolet observes photons emitted with energies of 0.3 ev, 0.5 ev, 0.8 ev, 2.0ev, 2.5ev, and 2.8ev. these are the only photon energies observed. (a) draw and label a possible energy-level diagram for one of the microscopic objects, which has four bound states. on the diagram, indicate the transitions corresponding to the emitted photons. explain briefly. (b) would a spring–mass model be a good model for these microscopic objects? why or why not? (c) the material is now cooled down to a very low temperature, and the photon detector stops detecting photon emissions. next, a beam of light with a continuous range of energies from infrared through ultraviolet shines on the material, and the photon detector observes the beam of light after it passes through the material. what photon energies in this beam of light are observed to be significantly reduced in intensity (“dark absorption lines”)? explain briefly.

9.98 kg of r-134a at 300 kpa fills a rigid container whose volume is 14 l. determine the temperature and total enthalpy in the container. the container is now heated until the pressure is 600 kpa. determine the temperature and total enthalpy when the heating is completed. use data from the steam tables.