When (R)-2-chloro-3-methylbutane is treated with potassium tert-butoxide, a monosubstituted alkene is obtained. When this alkene is treated with HBr, a mixture of products is obtained. Identify all of the expected products.

See explanation and image attached

Explanation:

The reaction of (R)-2-chloro-3-methylbutane with potassium tert-butoxide yields a monosubstituted alkene .

Since the base is bulky, the Hoffman product predominates because attack occurs at the less hindered carbon atom to yield the major product as shown.

The alkene reacts with HBr at the secondary carbon atom to yield a carbocation intermediate which is flat and planar. Attack on either face of the carbocation yields a racemic mixture of the (2R) and (2S) products.

Rearrangement of the carbocation to yield a tertiary carbocation gives the 2-bromo-2-methyl butane product as shown in the image attached.

if the concentration of products is decreased, the equilibrium will shift toward the products). add an inert gas (one that is not involved in the reaction) to the constant-volume reaction mixture: this will increase the total pressure of the system, but will have no effect on the equilibrium condition.

explanation: