In the titration of NaOH with vinegar, a student overshot the endpoint (i. e. added too much NaOH solution). How will this affect the calculate percent acetic acid in the vinegar

Overshooting the endpoint leads to a percent acetic acid in vinegar higher than the correct value.

Explanation:

When too much NaOH solution is added, the resulting number of equivalent hydronium (OH⁻) will be higher than what it is in reality. This would directly lead to the number of acetic acid moles in the vinegar being found higher than normal.

the dissociation of nickel hydroxide is follows:

the concentration of hydroxide ion is

the equilibrium constant value of nickel hydroxide is = 6.1 * 10^-^1^6 and thus equilibrium equation can be written as:

thus, concentration of ni is 0.23 * 10^-^4 mol /l