Be sure to answer all parts. Exactly 100 mL of 0.15 M nitrous acid (HNO2) are titrated with a 0.15 M NaOH solution. (a) Calculate the pH for the initial solution. (b) Calculate the pH for the point at which 80.0 mL of the base has been added. (c) Calculate the pH for the equivalence point. (d) Calculate the pH for the point at which 105 mL of the base has been added.

as given the equation is

2al + 6 hcl > 2 alcl3 + 3 h2(g)

as per equation two moles of aluminum reacts with six moles of hcl to give two moles of alcl3 and three moles of hydrogen gas

given: three moles of al are present and 7 moles of hcl

for three moles of aluminum nine moles of hcl will be required

however as 7 moles of hcl are present so the limiting reagent is hcl

hcl is going to decide the number of moles of product formed

when six moles of hcl are present = 3 moles of h2 are formed

when one mole of hcl is present == 3/6 mole sof h2 will be formed

when 7 moles of hcl are present = 3 x 7/ 6 moles of h2 will be formed = 3.5 moles of h2