Chemistry, 28.01.2020 01:31 milkshakegrande101

Select the structural formula(s) for the product(s) obtained when 1-butene reacts with hg(oac)2 in thf and h2o, then nabh4, oh-.

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Answer from: witcol386

CH3CH2CH(OH)CH3

Explanation:

This reaction follows the Markonikovs rule which states that the addition of an acid yo an assymetric alkene, the proton given off by the acid goes to the Carbon attached/with more hydrogen substituents and the rest of the acid ion goes to the Carbon with more alkyl substituents.

The reaction under goes 2 steps,

The first step called Oxymercuration involves the dissociation of Hg(OAc)2 into HgOAc+ and OAc-. The double bond in 1-butene (high electron site) bonds to an electron deficient HgOAc+ thereby forming an unstable complex, the lone pairs of oxygen in the water molecule (H2O) is attracted and a conplex is further formed with a proton on the now bonded H2O molecule.

To stabilise this, the proton(H+) is removed and then Deoxymercuration occurs. Deoxymercuration is simply removing the HgOAc+ molecule from the compound. This is done by the further reaction with the mixture of NaBH4 in alkaline medium; this is a string reducing reagent (reducting reagent - addition of excess Hydrogen) to form a secondary alcohol(Butan-2-ol)

Below us the mechanism in the attachment, i hope this was helpful.

Select the structural formula(s) for the product(s) obtained when 1-butene reacts with hg(oac)2 in t

Answer from: Quest

answer: - 3.) the oxidation state of nitrogen in no changes from +2 to 0, and the oxidation state of carbon in co changes from +2 to +4 as the reaction proceeds.

solution: - as per the rules, oxidation number of oxygen in its compounds is -2. the sum of oxidation numbers of all the elements of a molecule or compound is zero.

also, the oxidation number in elemental form is zero.

in no, the oxidation number of o is -2 so the oxidation number of n is +2 so that the sum is zero.

similarly, the oxidation number of c in co is +2 and o is -2.

on product side the oxidation number of n is 0 as it is in the elemental form( $n_2$ ) .

oxidation number of c in carbon dioxide is +4 as there are two oxygen in it and we know that each oxygen is -2.

so, oxidation number of n is changing from +2 to 0 and the oxidation number of c is changing from +2 to +4.

since nitrogen is reduced and hence no is acting as an oxidizing agent. carbon is oxidized and so co is acting as a reducing agent.

so, the right choice is number 3.)the oxidation state of nitrogen in no changes from +2 to 0, and the oxidation state of carbon in co changes from +2 to +4 as the reaction proceeds.

Answer from: Quest

They carry out the exchange of gases as we breathe ( oxygen and carbon dioxide).

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Select the structural formula(s) for the product(s) obtained when 1-butene reacts with hg(oac)2 in t...

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