Can someone explain abs show work for both part a and b please

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

An automobile steering wheel is shown. what is the ideal mechanical advantage? if the ama is 8, what is the efficiency of the steering wheel?

Determine the net charge of the predominant form of arg at (a) ph 1.0, (b) ph 5.0, (c) ph 10.5, and (d) ph 13.5