How are an atom of calcium-48 and an atom of calcium-47 different?

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

Consider a one meter long horizontal pipe with a constant 100 cm^2 cross sectional area. water flows rightward into the pipe at x = 0 with flow velocity 02m/sec at every point within the pipe intake area. at x=1, the rightward flow rate is 0.192 m/sec. assume the water is a conserved quantity in the pipe, so there must be a leak (a sink) somewhere in the pipe. 1. compute net volumetric flow of the source if the system to be in equilibrium. 2. now assume the pipe in the problem has no leaks. compute the net volumetric rate of change for the system.

Jenny wants to test the electrical conductivity of two substances dissolved in water. she is preparing the containers for the experiment. which factor is most important for her to control? a) volumes of the solutions b) appearance of the solutions c) temperatures of the solutions d) concentrations of the solutions