Can gas pressure sometimes be greater than atmospheric pressure?​

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

In positive numbers less than 1, the zeros between the decimal point and a non-zero number are blank significant

4r-134a enters the condenser of a residential heat pump at 800 kpa and 50°c at a rate of 0.022 kg/s and leaves at 750 kpa subcooled by 3°c. the refrigerant enters the compressor at 200 kpa superheated by 4°c determine (a) the isentropic efficiency of the compressor, (b) the rate of heat supplied to the heated room, and (c) the cop of the heat pump. also, determine (d) the cop and rate of heat supplied to the heated room if this heat pump operated on the ideal vapor-compression cycle between the pressure limits of 200 and 800 kpa. (0.757, 4.37 kw, 5.12, 6.18, 3.91 kw)