Tin can get crushed when heated with lid open and cooled. why?​

The energy released by a chemical reaction can be measured using a calorimeter. when barium hydroxide octahydrate crystals are reacted with dry ammonium chloride inside of a coffee cup calorimeter, the temperature of the 18.00 g of water in the calorimeter decreases from 30.0°c to 8.0°c. the equation for calculating energy absorbed or released by a reaction is: where q is the energy released or absorbed, m is the mass of water in the calorimeter, cp is the specific heat of water, and δt is the observed temperature change. if the specific heat of liquid water is 4.19 j/g·°c, how much energy was absorbed by the reaction?

Ineed the answer to question 1 , i’m desperate

Suppose a comet has an orbital period of 309.1 years around the sun. what is it’s average distance from the sun?