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The pressure, volume, and temperature of a mole of an ideal gas are related by the equation pv = 8.31t, where p is measured in kilopascals, v in liters, and t in kelvins. use differentials to find the approximate change in the pressure if the volume increases from 14 l to 14.6 l and the temperature decreases from 375 k to 370 k. (round the answer to two decimal places.)

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

Which law represents the thermodynamic statement of the conservation of energy of a system? a. the fourth law b. the first law c. the second law d. the third law