Help pls I’m dying I don’t understand HELP ASAP-

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

Asap and show ! a 14 kg rock starting from rest free falls through a distance of 5.0 m with no air resistance. find the momentum change of the rock caused by its fall and the resulting change in the magnitude of earths velocity. earth mass is 6.0 * 10^24 kg. show your work assuming the rock earth system is closed.

Because air contracts as it cools, the air pressure inside a freezer is typically lower than on the outside. why do ice cubes inside a freezer tend to shrink over time? a. the ice dissolves oxygen from the air, forming a denser crystalline matrix.b. the ice reacts chemically with carbon dioxide in the air, forming gaseous carbon compounds.c. the ice melts, and then the liquid freezes as ice crystals on the bottom of the freezer.d. the ice sublimes, and then the water vapor deposits as ice crystals on the sides of the freezer.