A 50 gram sample of delicious pork rinds is placed in an open, constant pressure calorimeter that contains 3000 grams of water. The temperature of the water increases by 47◦C when the pork rinds are combusted. The heat capacity of water is 4.184 J/g ◦C. Assume the heat lost to the calorimeter itself or to the air is negligible. Which of the following is correct for the SYSTEM?

1. ∆U = −11.8 kJ
2. ∆H = +11.8 kJ
3. ∆U = +11.8 kJ
4. ∆H = +590 kJ
5. ∆H = −590 kJ
6. ∆H = −11.8 kJ
7. ∆U = −590 kJ
8. ∆U = +590 kJ