Based on how the book describes a heat pump in sec 16.3 how does a heat pump prove law of conservation of energy

What happens to atoms and chemical bonds during a reaction?

Acoal-fired plant generates 600 mw of electric power. the plant uses 4.8 x 10^6 kg of coal each day, and the heat of combustion of coal is 3.3x 10^7 j/kg. the steam that drives the turbines is at a temperature of 300° c, and the exhaust water is at 37° c. (a) what is the overall efficiency of the plant for generating electric power? (b) how much thermal energy is exhausted each day? (c) what is the change in entropy of the universe for this heat engine? (d) using the same heat reservoirs, what is the maximum possible (carnot) efficiency for a heat engine?

After a big snowfall, you take your favorite rocket-powered sled out to a wide field. the field is 195 m across, and you know that your sled accelerates at a rate of 3.65 m/s2 when the rocket is on. how much time will it take the sled to cross the field starting from rest, assuming the rocket is on the whole time?