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Consider the first overtone vibrational band of the 11b19f molecule within the harmonic oscillator, rigid-rotor approximation. the harmonic vibrational frequency and rotational constant of this isotopomer are equal to 1402.13 cm-1 and 1.50724 cm-1 , respectively. determine the frequency (in cm-1 ) of the j = 5 → 6 r-branch transition in the 1-st overtone. what gives rise to vibrational overtones?
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Consider the first overtone vibrational band of the 11b19f molecule within the harmonic oscillator,...
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