Given that δgo for a reaction is 8.00 kcal mol-1, what is the value of keq at 25oc (i. e., 77of)? the value of r is 0.008314 kj/mol k or 0.001986 kcal/mol k. report your answer to three significant digits.

An internally reversible refrigerator has a modified coefficient of performance accounting for realistic heat transfer processes of where qin is the refrigerator cooling rate, qout is the heat rejection rate, and is the power input. show that copm can be expressed in terms of the reservoir temperatures tc and th, the cold and hot thermal resistances rt,c and rt,h, and qin, as where rtot rt,c rt,h. also, show that the power input may be expressed as 1.39 a household refrigerator operates with cold- and hot-temperature reservoirs of tc 5 c and th 25 c, respectively. when new, the cold and hot side resistances are rc,n 0.05 k/w and rh,n 0.04 k/w, respectively. over time, dust accumulates on the refrigerator’s condenser coil, which is located behind the refrigerator, increasing the hot side resistance to rh,d 0.1 k/w. it is desired to have a refrigerator cooling rate of qin 750 w. using the results of problem 1.38, determine the modified coefficient of performance and the required power input w under (a) clean and (b) dusty coil conditions. internally reversible refrigerator qout qin w high-temperature reservoir low-temperature reservoir th th,i tc,i tc high-temperature side resistance low-temperature side resistance w qin th tc qinrtot tc qinrtot copm tc qinrtot th tc

5submission this assignment is worth 20 points total. you are required to submit the following by next lab: 1. (3 points) determine the equation for the output angular velocity ω2 = θ˙ 2 as a function of θ1, ω1 = θ˙ 1 and α. you must show all your work to receive credit. 2. (2 points) use the result of problem#1 to plot ω2 over 0 ≤ θ1 ≤ 360deg with ω1 = 360deg/sec. do this for α = {10,30}deg. show the results on the same plot and properly label the axes, title, legend. for this you can use matlab or ms excel. 3. (3 points) determine the equation for the output angular acceleration ω˙ 2 and create a plot similar to the one in problem#2. 4. (10 points) submit plots of the results (ω2 and ω˙ 2) obtained from creo/mechanism and compare them to results of problem#2 and problem#3. note that you should do these comparisons for the two cases with α = {10,30}deg. 5. (2 points) provide a brief explanation of the results. did they match? what are the implications as misalignment angle increases?

The magnitude of the amount of energy released by burning a fuel source, measured in energy per unit mass, is called its fuel value. note that the fuel value is the negative of the isobaric specific heat of combustion for the fuel. if all the energy obtained from burning 1.23 pounds of butane with a fuel value of 10.85 kcal/g is used to heat 128.0 kg of water at an initial temperature of 18.3 °c, what is the final temperature? note that 1 lb = 453.6 g.