Why doesn't cloud formation take place until the dew point temperature is reached

Your 249 ml cup of coffee is too hot to drink when served at 82 degree celsius. what is the mass of an ice cube taken from a -21 degree celsius freezer, that will cool your coffee to a pleasant 54 degree celsius. specific heat of the water is 4190 j/kg c, specific heat of ice is 2090 j/kg c, heat of fusion of ice is 3.33 x 10^5 j/kg

Anybody wanna ? (picture included? )

Under normal conditions, describe how increasing the temperatures effects the solubility of a typical salt