Aprocedure used to find the volume of a rock

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

If the new moon happens on january 15th, what shape will it be on february 6th?

Air is contained in a variable-load piston-cylinder device equipped with a paddle wheel. initially, air is at 400 kpa and 17°c. the paddle wheel is now turned by an external electric motor until 75 kj/kg of work has been transferred to air. during this process, heat is transferred to maintain a constant air temperature while allowing the gas volume to triple. calculate the required amount of heat transfer in kj/kg.