I need help on this problem

Which pair of angles are vertical angles? ∠1 and ∠4 ∠1 and ∠2 ∠2 and ∠4 ∠2 and ∠3

Aswimming pool had 2.5 million liters of water in it. some water evaporated, and then the pool only had 22 million liters of water in it. what percent of the water evaporated?

Plz answer asap! i will reward brainliest and 12 points for these three questions!take notice: these three questions are completely different! 1) what is the percentage of sugar in the syrup made of 10 kg of water and 4 kg of suugar? 2) what was the original price if after 10% discount it became $450? 3) at first a price was decreased by 12%, then it was disounted again by an additional 5%. what is the percent of the total discount? , and remeber i will award brainliest and 12 points!