A heating pad takes 2,812 Watts during each time it is turned on. If you only use it for 16 minutes, how much CO2 was created? Round to 1 decimal,

A3cm×3cm\greend{3\,\text{cm} \times 3\,\text{cm}} 3cm×3cm start color greend, 3, space, c, m, times, 3, space, c, m, end color greend rectangle sits inside a circle with radius of 4cm\blued{4\,\text{cm}} 4cm start color blued, 4, space, c, m, end color blued . what is the area of the shaded region? round your final answer to the nearest hundredth.