Which graph decreases crosses the y axis at (0,7) and then increases

The ratio pv to nrt is plotted against pressure for ch4 at 0°c and 200°c. why does the curve for 0°c drop below the horizontal line for an ideal gas whereas the curve for 200°c does not?

Jacob signs up to work for 2 1/2 hours at the school carnival. if each work shift is 3/4 hour, how many shifts will jacob work? (i just want to double check : |, for anybody that responds! : )

For what value of (y) is 3^3/3^y =1/9