The chariot was first used as s weapon by the

I believe that the Egyptians were the first to use the chariot in warfare.

They had invented the yoke saddle for their chariot horses way, way back in 1500. As a common rule, the Egyptians had used their chariots as running archery platforms, and chariots had always had two men, the driver steering the chariot, and the archer directed his arrow fire at any targets that were within general shooting range.

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-Pepetreefrogthe2nd