How does temperature effect the states of matter?

Two flowing streams of argon gas are adiabatically mixed to form a single flow/stream. one stream is 1.5 kg/s at 400 kpa and 200 c while the second stream is 2kg/s at 500 kpa and 100 ? . it is stated that the exit state of the mixed single flow of argon gas is 150 c and 300 kpa. assuming there is no work output or input during the mixing process, does this process violate either the first or the second law or both? explain and state all your assumptions.

Water at the rate of 1 kg/s is forced through a tube with a 2.5 cm inner diameter. the inlet water temperature is 15°c, and the outlet water temperature is 50°c. the tube wall temperature is 14°c higher than the local water temperature all along the length of the tube. what is the length of the tube?

Liquid flows at steady state at a rate of 2 lb/'s through a pump, which operates to raise the elevation of the liquid 100 ft from control volume inlet to exit. the liquid specific enthalpy at the inlet is 40.09 btu/lb and at the exit is 40.94 btub. the pump requires 3 btu/s of power to operate. if kinetic energy effects are negligible and gravitational acceleration is 32.174 tt/s, the heat transfer rate associated with this steady state process is most closely 1)-2,02 btu/s from the liquid to the surroundings 2)-3.98 btu/s from the surroundings to the liquid. 3)-4.96 btu/s from the surroundings to the liquid. 4)-1.04 btu/s from the liquid to the surroundings.