Write the combined first law of thermodynamics of Gibbs free energy for a multicomponent system with an interface, explain the meaning of each term

Carbon dioxide gas expands isotherm a turbine from 1 mpa, 500 k at 200 kpa. assuming the ideal gas model and neglecting the kinetic and potential energies, determine the change in entropy, heat transfer and work for each kilogram of co2.

Agas contained within a piston-cylinder assembly e end nation about same energy states, 1 and 2, where pi 10 bar, v undergoes two processes, a and b, between the sam 0.1 m3, ui-400 kj and p2 1 bar, v2 1.0 m2, u2 200 kj: process a: process from 1 to 2 during which the pressure- volume relation is pv constant process b: constant-volume process from state 1 to a pressure of 2 bar, followed by a linear pressure-volume process to +20 0 state 2 kinetic and potential energy effects can be ignored. for each of the processes a and b, (a) sketch the process on p-v coordinates, (b) evaluate the work, in kj, and (c) evaluate process the heat transfer, in kj

Determine (a) the maximum thermal efficiency of reversible power cycles operating between a hot reservoir at 1000°c and a cold reservoir at 200°c and (b) the maximum cops for reversible refrigeration and heat pump cycies, respectively, between 28°c and 14°c.