For the solidification of iron, calculate the critical radius r* and the activation free energy ΔG* if nucleation is homogeneous. Values for the latent heat of fusion and surface free energy are –1.85 × 109 J/m3 and 0.204 J/m2, respectively. Use the supercooling value ΔT = 291 K, and the melting point of iron is 1538°C. Calculate the number of atoms found in a nucleus of critical size. Assume a lattice parameter of 0.292 nm for solid iron at its melting temperature.

Ashielded metal arc-welding operation is accomplished in a work cell by a fitter and a welder. the fitter takes 5.5 min to load components into the welding fixture at the beginning of the work cycle, and 1.5 min to unload the completed weldment at the end of the cycle. the total ength of the weld seams 1200 mm, and the travel speed used by the welder averages 300 mm/min. every 600 mm of seam length, the welding stick must be changed, which takes 0.8 min. while the fitter is working, the welder is idle (resting): and while the welder is working the fitter is idle. (a) determine the average arc-on time as a fraction of the work cycle time. (b) how much improvement in arc-on time would result if the welder used flux-cored arc welding (manually operated), given that the spool of weld wire must be changed every 10 weldments, and it takes the welder 5.0 min to accomplish the change? (c) what are the production rates for these two cases (weldments completed per hour)? attach your work and solutions.