Mass spectral measurements were made on 10 replicate low concentration Pb-EDTA samples: 190.5 190.5 , 146.2 146.2 , 160.9 160.9 , 175.9 175.9 , 144.9 144.9 , 214.3 214.3 , 165.9 165.9 , 170.5 170.5 , 159.9 159.9 , and 177.5 177.5 counts. Ten measurements of a blank had a mean measurement of 44.3 44.3 counts. A sample containing 3.00 3.00 μM Pb-EDTA gave a measurement of 1777 1777 counts. Estimate the signal and detection limit for Pb-EDTA.

Water at 55c flows across a flat plate whose surface temperature is held constant at 95c. if the temperature gradient at the plate's surface for a given value of x is 18 c/mm, find a) local heat transfer coefficient. b) heat flux

A3-mm-thick panel of aluminum alloy (k 177 w/m-k, c 875 j/kg-k and ? = 2770 kg/m) is finished on both sides with an epoxy coating that must be cured at or above t,-150°c for at least 5 min. the production line for the curing operation involves two steps: (1) heating in a large oven with air at ts,0-175°c and a convection coefficient of h, 40 w/m2. k, and (2) cooling in a large chamber with air at 25°c and a con- vection coefficient of he 10 w/m2.k. the heating portion of the process is conducted over a time interval te which exceeds the ime required to reach 150°c by 5 min (h = r + 300 s). the coating has an emissivity of ? = 0.8, and the temperatures of the oven and chamber walls are 175 and 25°c, respectively. if the panel is placed in the oven at an initial temperature of 25°c and removed from the chamber at a safe-to-touch tempera ture of 37°c, what is the total elapsed time for the two-step curing operation?

10 kg of co2 is initially contained at 400 kpa and 300 k. the gas constant for carbon dioxide is 189 j/lkg k) and has a specific heat ratio, k, of 1.289. isentropic expansion then occurs until the pressure is 200 kpa. a) determine the initial volume of co2 in m. b) determine the final temperature in k. c) determine the work done by the system during the expansion kl.