The number of vacancies present in some metal at 757°C is 1.7 × 1024 m–3. Calculate the number of vacancies at 470°C given that the energy for vacancy formation is 1.17 eV/atom; assume that the density at both temperatures is the same.

Amass of m 1.5 kg of steam is contained in a closed rigid container. initially the pressure and temperature of the steam are: p 1.5 mpa and t 240°c (superheated state), respectively. then the temperature drops to t2= 100°c as the result of heat transfer to the surroundings. determine: a) quality of the steam at the end of the process, b) heat transfer with the surroundings. for: p1.5 mpa and t 240°c: enthalpy of superheated vapour is 2900 kj/kg, specific volume of superheated vapour is 0. 1483 m/kg, while for t 100°c: enthalpy of saturated liquid water is 419kj/kg, specific volume of saturated liquid water is 0.001043m/kg, enthalpy of saturated vapour is 2676 kj/kg, specific volume of saturated vapour is 1.672 m/kg and pressure is 0.1 mpa.

Asimple rankine cycle uses water as the working fluid. the water enters the turbine at 10 mpa and 480c while the condenser operates at 6 kpa. if the turbine has an isentropic efficiency of 80 percent while the pump has an isentropic efficiency of 70 percent determine the thermal efficiency

10 kg of co2 is initially contained at 400 kpa and 300 k. the gas constant for carbon dioxide is 189 j/lkg k) and has a specific heat ratio, k, of 1.289. isentropic expansion then occurs until the pressure is 200 kpa. a) determine the initial volume of co2 in m. b) determine the final temperature in k. c) determine the work done by the system during the expansion kl.