Acylinder with a piston restrained by a linear spring contains 2 kg of carbon dioxide at 500 kpa and 400°c. it is cooled to 40°c and 300 kpa. calculate the heat transfer for the process.

heat transfer for the process is - 643.3 kJ

Explanation:

given data

mass m = 2 kg

pressure p1 = 500 kPa

temperature t1 = 400°C = 673.15 K

temperature t2 = 40°C = 313.15 K

pressure p2 = 300 kPa

to find out

heat transfer for the process

solution

we know here mass is constant so

m1 = m2

so by energy equation

m ( u2 - u1 ) = Q - W

Q is heat transfer

and in process  P =  A+ N that is linear spring

so

W = ∫PdV

= 0.5 ( P1+P2) ( V1 - V2)

so for case 1

P1V1 = mRT

put here value

500 V1 = 2 (0.18892) (673.15)

V1 = 0.5087 m³

and

for case 2

P2V2 = nRT

300 V2 = 2 (0.18892) (313.15)

V2 = 0.3944 m³

and

here W will be

W = 0.5 ( 500 + 300 ) ( 0.3944 - 0.5087 )

W = -45.72 kJ

and

Q is here for Cv = 0.83 from ideal gas table

Q = mCv ( T2-T1 ) + W

Q = 2 × 0.83 ( 40 - 400 ) - 45.72

Q = - 643.3 kJ

heat transfer for the process is - 643.3 kJ