How is entropy defined on a differential basis? (use an equation)?

Amass of m 1.5 kg of steam is contained in a closed rigid container. initially the pressure and temperature of the steam are: p 1.5 mpa and t 240°c (superheated state), respectively. then the temperature drops to t2= 100°c as the result of heat transfer to the surroundings. determine: a) quality of the steam at the end of the process, b) heat transfer with the surroundings. for: p1.5 mpa and t 240°c: enthalpy of superheated vapour is 2900 kj/kg, specific volume of superheated vapour is 0. 1483 m/kg, while for t 100°c: enthalpy of saturated liquid water is 419kj/kg, specific volume of saturated liquid water is 0.001043m/kg, enthalpy of saturated vapour is 2676 kj/kg, specific volume of saturated vapour is 1.672 m/kg and pressure is 0.1 mpa.

Avolume of 2.65 m3 of air in a rigid, insulated container fitted with a paddle wheel is initially at 264 k, 5.6 bar. the air receives 432 kj by work from the paddle wheel. assuming the ideal gas model with cv = 0.71 kj/kg • k, determine for the air the amount of entropy produced, in kj/k

Atank with constant volume contains 2.27 kg of a mixture of water phases (liquid-vapor). in the initial state the temperature and the quality are 127 °c and 0.6, respectively. the mixture is heated until the temperature of 160 oc is reached. illustrate the process in a t-v diagram. then, determine (1) the mass of the vapor in kg at the initial state, (2) the final pressure in kpa.