What volume of so2 is produced at 325 k and 1.35 atm when 15.0 grams of hcl reacts with excess k2so3?

The volume of SO2 produced at 325k   is calculated as  below

calculate  the moles of SO2 produced  which  is calculated as follows

write the  reacting equation
K2SO3 +2 HCl = 2KCl +H2O+ SO2

find the   moles  of  HCl  used
=mass/molar mass = 15g/ 36.5 g/mol =0.411 moles

by  use of mole ratio between  HCl to  SO2  which is  2:1 the moles of SO2 is therefore = 0.411 /2 =0.206  moles  of SO2

use the idea  gas  equation  to calculate the volume SO2
that is V=nRT/P  
where  n=0.206  moles
          R(gas constant) = 0.082 L.atm/ mol.k
         T=325 K
          P=1.35 atm

V=(0.206 moles x  0.082 L.atm/mol.k x325 k)/1.35 atm = 4.07 L of SO2

The answer is b because a,c,and d are opinons