Which compound will precipitate first: caso4 ( ksp = 2.4×10−5) or ag2so4 ( ksp = 1.5×10−5)?   how much  na2so4  solution must be added to initiate the precipitation? i know the answer to the first part but not the second

Caso4(s) < > ca+2 + so4^-2 ksp = [ca+2][so4^-2] = 2.4 x 10^-5 = [0.20][so4^-2] [so4^-2] =1.2 x 10^-4 ag2so4(s) ,> 2ag+ + so4^-2 ksp = [ag+]^2[so4^-2] = 1.5 x 10^-5 = (0.30)^2[so4^-2] [so4^-2] = 1.5 x 10^-5/0.09 = 1.7 x 10^-4 caso4 would precipitate first since it requires less so4^- to form a saturated solution.  i believe this is right, i hope it !  

Google it that might work

Temperature and pressure