Can someone help me with this

explanation:

let the different atoms be x and y. each with four protons and same mass will be represented as follows.

mass number is number of protons + number of neutrons.

            and  

since, it is given that one has a negative charge while the other is neutral. therefore, there will be increase in number of protons and the atom will be represented as follows.

according to periodic table, mass number of beryllium is 9 and it has atomic number 4 so, the atoms will be and .  

the protons and neutrons will be located inside the nucleus whereas the electrons will be revolving around the nucleus.  

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.