What is the pressure in a 13.0-L cylinder filled with 39.9 g of oxygen gas at a temperature of 334 K ? Express your answer to three significant figures with the appropriate units.

The answer to your question really depends on three things: how much water you have, how cold it is to start out, and how cold the things around it are. water actually freezes when it gets to 32 degrees fahrenheit (0 degrees celsius), but the time it takes to get there may be different.  let's start with the first. if you take two glasses, and fill one with a tiny bit of water, and the other about halfway, then put them both in the freezer, the one with less water will freeze first (you can try this at home, but i recommend using plastic cups and not glass ones).  now let's move on to the second part. let's say you have two glasses, and you fill one with really cold water that has been in the refrigerator, and the other with really hot water from the sink. if you put both of them in the freezer, the one that started out colder will freeze first.  for the third part, let's imagine that you have two glasses with the same amount of water in them, and the water is at the same temperature. imagine putting one outside on a really really cold day in georgia, and having a friend in alaska put one outside on the same day. since it would be so much colder in alaska, the glass of water there would freeze before yours.  so, if you took a tiny bit of really cold water in a glass, and put it outside on a cold day in alaska, it would freeze a lot faster than a big glass of hot water outside on a cold day in georgia. 

Answerthis solution will not form a precipitateexplanationsolubility equilbrium:         pbf₂(s)  ⇄ pb²⁺(aq) + 2 f⁻(aq)the solubility product expression is    (we exclude solids from the equilibrium expression).now suppose we have the trial ion product q, which we can define as    then, we can interpret  q as the product of the concentration of the ions that we have and ksp as the product of the ion concentrations that are needed to form a saturated solution.if q > ksp, then that implies that there will be a surplus of ions that exceed the amount that is required to form a saturated solution. a precipitate will then form (the precipitate continually  forms until the surplus ions are removed and q is decreased to ksp's value).if q = ksp, the saturated solution that forms is barely saturated and the precipitate will be minimal.if q < ksp, then the ion concentration will not be enough to form a saturated solution (so no precipitate).using our information, we calculate the trial ion product:     since q = 2.7  × 10⁻⁸ < ksp =  4  ×  10⁻⁸, a precipitate will not form.