Calculate the pH of a solution prepared by mixing 0.080 0 mol of chloroacetic acid plus 0.040 0 mol of sodium chloroacetate in 1.00 L of water. (Assume pKa = 2.866 and Kw = 1.01 ✕ 10−14). (a) First do the calculation by assuming that the concentrations of [HA] and [A-] equal their formal concentrations.
(b) Then do the calculation, using the real values of [HA] and [A-] in the solution.
(c) Using f rst your head, and then the Henderson-Hasselbalch equation, f nd the pH of a solution prepared by dissolving all the all the following compounds in one beaker containing a total volume of 1.00 L: 0.174 mol ClCH2CO2H, 0.026 mol ClCH2CO2Na, 0.074 mol HNO3, and 0.074 mol Ca(OH)2. Assume that Ca(OH)2 dissociates completely.

So what you would do is go through and add 3 teaspoons(tsp) 6 times because of the 6 tablespoons(tbsp). which will give you an answer of 18. another way is to multiply 3x6=18.

The answer to your question really depends on three things: how much water you have, how cold it is to start out, and how cold the things around it are. water actually freezes when it gets to 32 degrees fahrenheit (0 degrees celsius), but the time it takes to get there may be different.  let's start with the first. if you take two glasses, and fill one with a tiny bit of water, and the other about halfway, then put them both in the freezer, the one with less water will freeze first (you can try this at home, but i recommend using plastic cups and not glass ones).  now let's move on to the second part. let's say you have two glasses, and you fill one with really cold water that has been in the refrigerator, and the other with really hot water from the sink. if you put both of them in the freezer, the one that started out colder will freeze first.  for the third part, let's imagine that you have two glasses with the same amount of water in them, and the water is at the same temperature. imagine putting one outside on a really really cold day in georgia, and having a friend in alaska put one outside on the same day. since it would be so much colder in alaska, the glass of water there would freeze before yours.  so, if you took a tiny bit of really cold water in a glass, and put it outside on a cold day in alaska, it would freeze a lot faster than a big glass of hot water outside on a cold day in georgia.