Draw a detailed mechanism for each of the two steps in the preparation of ethyl-3- coumarincarboxylate (2).

Which element in the third period would you expect to have the larger atomic radius, sodium (na) or sulfur (s)? a. sodium, because it has a higher effective nuclear charge attracting electrons in fewer energy levels. b. sodium, because it has fewer protons attracting electrons in the same energy levels. c. sulfur, because it has more protons attracting electrons in more energy levels. d. sulfur, because it has a higher effective nuclear charge attracting electrons in the same energy levels.

If i initially have a gas at a pressure of 12 atm, a volume of 23 liters, and a temperature of 200 k, and then i raise the pressure to 14 atm and increase the temperature to 300 k, what is the new volume of the gas?

Answer asap need by wednesday morning explain how a buffer works, using an ethanoic acid/sodium ethanoate system including how the system resists changes in ph upon addition of a small amount of base and upon addition of a small amount of acid respectively. include the following calculations in your i. calculate the ph of a solution made by mixing 25cm3 0.1m ch3cooh and 40cm3 0.1m ch3coo-na+. [ka = 1.74 x 10-5 m] ii. calculate the ph following the addition of a 10cm3 portion of 0.08 m naoh to 500cm3 of this buffer solution. iii. calculate the ph following the addition of a 10cm3 portion of 0.08 m hcl to 200cm3 of the original buffer solution.