Aldehydes and ketones are converted into alkenes by means of a direct nucleophilic addition called the Wittig reaction, In the reaction, a triphenylphosphorine ylide, also called a phosphorane, adds to an aldehyde/ketone to give a four-membered cyclic intermediate called an is not isolated but instead spontaneously decomposes to release triphenylphosphine oxide and an alkene The ylide is formed by reaction of triphenylphosphine, a good nucleophile, with a primary alkyl halide in an Sy2 reaction, followed by deprotonation of the carbon with a strong base, such as butylithium. The carbonyl carbon and the carbon originally bonded to the halogen become the two carbons with the double bond in the product alkene The real value of the Wittig reaction lies in its ability to yield an alkene of predictable structure, as the c-c bond is precisely where the C bond was in the reactant and no isomers (other than E/Z isomers) are formed Draw curved arrows to show the movement of electrons in this step of the mechanism.
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Chemistry, 21.06.2019 17:00
An aqueous solution of hydroiodic acid is standardized by titration with a 0.186 m solution of calcium hydroxide. if 26.5 ml of base are required to neutralize 20.3 ml of the acid, what is the molarity of the hydroiodic acid solution? m hydroiodic acid
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Chemistry, 21.06.2019 18:00
In a sample of oxygen gas at room temperature, the average kinetic energy of all the balls stays constant. which postulate of kinetic molecular theory best explains how this is possible? a. attractive forces between gas particles are negligible because the particles of an ideal gas are moving so quickly. b. collisions between gas particles are elastic; there is no net gain or loss of kinetic energy. c. gases consist of a large number of small particles, with a lot of space between the particles. d. gas particles are in constant, random motion, and higher kinetic energy means faster movement.
Answers: 1
Chemistry, 22.06.2019 02:40
For a patient with the following pes statement and interventions, which would be the most appropriate monitoring and evaluating data? pes statement: inadequate calcium intake related to food and nutrition related knowledge deficit as evidenced by statements that the only dietary source of calcium is milk and she believes that she is lactose intolerant. patient’s nutrition prescription is for a diet providing 1200 mg calcium per day. patient was provided with in-depth nutrition education on alternative dietary and supplement sources of calcium. a. calcium intake (at subsequent visit) b. knowledge assessment by asking patient to identify food sources from menus and shopping list (at the end of the current visit) c. serum calcium (at next visit) d. both a and b e. both a and c
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Aldehydes and ketones are converted into alkenes by means of a direct nucleophilic addition called t...
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