PLEASE HELP MEEE THIS IS FOR a gradE AND IF I FAIL I FaIL THIS CLASs HELP ME

What happens to energy in an open system?

How many mmols of tris-hcl are there in 100 ml of a 100 mm tris-hcl buffer solution at ph 8.1? note that the 100 mm refers to the sum of tris and tris-hcl concentrations?

A4.86 g piece of metal was placed in a graduated cylinder containing 15.5 ml of water. the water level rose to 17.3 ml. what is the density of the metal. i need the steps of how to solve it to so i can use a formula to work out other problems.