Chemistry, 12.03.2021 01:10 deannajd03
18.) In basic aqueous solution, the iodide ion reacts with the hypochlorite ion via the generally agreed mechanism on the right:
a.) Identify all intermediates included in this mechanism.
OCl–(aq) + H2O (l) Ý HOCl (aq) + OH– (aq) fast
I– (aq) + HOCl (aq) ↓ HOI (aq) + Cl– (aq) slow
OH–(aq) + HOI (aq) ↓ H2O (l) + OI–(aq) fast
net rxn: I– (aq) + OCl–(aq) ↓ Cl–(aq) + OI–(aq)
b.) Write the rate law that this mechanism predicts for the overall reaction.
Answers: 3
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18.) In basic aqueous solution, the iodide ion reacts with the hypochlorite ion via the generally ag...
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