Please help me i dont get it

What is a metal replacement reaction

If you chip a tooth, most likely you will go to the dentist to have the missing material filled in. currently the material used to fill in teeth is a polymer that is flexible when put in, yet is hardened to the strength of a tooth after irradiation with blue light at a wavelength of 461 nm. what is the energy in joules for a photon of light at this wavelength?

In the following redox reaction which is the oxidizing agent and which is the reducing agent? alcl3 + na nacl + al oxidizing agent = reducing agent =