Is snow a mineral or no?

Kp is the equilibrium constant for dissociation of the propionic acid dimer. what is the sign of the slope for a plot of the natural logarithm of kp vs. inverse temperature for this reaction?

Is this correct if not can u correct me

Which aqueous solution of ki freezes at the lowest temperature? 1) 1 mol of ki in 500. g of water 2) 2 mol of ki in 500. g of water 3) 1 mol of ki in 1000. g of water 4) 2 mol of ki in 1000. g of water