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What is a metal replacement reaction

How many mmols of tris-hcl are there in 100 ml of a 100 mm tris-hcl buffer solution at ph 8.1? note that the 100 mm refers to the sum of tris and tris-hcl concentrations?

Ammonium perchlorate nh4clo4 is the solid rocket fuel used by the u.s. space shuttle. it reacts with itself to produce nitrogen gas n2 , chlorine gas cl2 , oxygen gas o2 , water h2o , and a great deal of energy. what mass of nitrogen gas is produced by the reaction of 2.1g of ammonium perchlorate?