Excess Aluminum reacts with 47.0 g of copper II Nitrate, what mass of copper could be produced?

Can someone me with questions 12 and 13 plz.

Why is the bond angle in a water molecule less than the bond angle of methane? a. the central oxygen atom in water has two lone pairs of electrons, whereas the central carbon atom in methane has no lone pairs. b. the central hydrogen atom in water has one lone pair of electrons, whereas the central carbon atom in methane has two lone pairs. c. the central oxygen atom in water has four lone pairs of electrons, whereas the central carbon atom in methane has only one lone pair. d. the central oxygen atom exerts more repulsive force on surrounding atoms than the central carbon atom in methane does. reset next

The comparison of the number of atoms in a copper coin the size of a penny with the number of people on earth is made to illustrate which of the following? a. that atoms are indivisible b. that atoms are very small c. that atoms are very large d. that in a copper penny, there is one atom for every person on earth