If a gas is cooled from 350k to 100 k and the new volume is kept constant, what is the final pressure if the original pressure was 300 mmHg?

a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.