Hello can someone pls help me with this question! ( About Balancing Chemical Equations Worksheet)

Draw two cyclic constitutional isomers of cis-1

100 grams of molten lead (600°c) is used to make musket balls. if the lead shot is allowed to cool to room temperature (21°c), what is the change in entropy (in j/k) of the lead? (for the specific heat of molten and solid lead use 1.29 j/g⋅°c; the latent heat of fusion and the melting point of lead are 2.45 × 104 j/kg and 327°c, respectively.)

Choose an equation that represents an enzyme-catalyzed reaction. (a) enzyme + substrate → enzyme-substrate complex (b) enzyme + substrate ←−→ enzyme + products (c) enzyme + substrate ←−→ enzyme-substrate complex → enzyme + products (d) enzyme + substrate ←−→ enzyme-substrate complex → enzyme-substrate complex + products