When 3243. grams of iron (III) chloride are reacted with 511.8 grams of hydrosulfuric acid, which is the limiting reactant? 2 FeCl3 + 3 H2S > Fe2S3 + 6 HCl

Hydrosulfuric acid will act as limiting reactant.

Explanation:

Given data:

Mass of iron(III) chloride = 3243.0 g

Mass of hydrosulfuric acid = 511.8 g

Limiting reactant = ?

Solution:

Chemical equation:

2FeCl₃ + 3H₂S       →       Fe₂S₃ + 6HCl

Number of moles of iron(III) chloride:

Number of moles = mass/molar mass

Number of moles = 3243.0 g/ 162.2 g/mol

Number of moles = 20 mol

Number of moles of hydrosulfuric acid:

Number of moles = mass/molar mass

Number of moles = 511.8 g/ 34.1 g/mol

Number of moles = 15 mol

Now we will compare the moles of both reactant with products

                      FeCl₃          :          Fe₂S₃

                       2                :            1

                      20               :          1/2 ×20 = 10

                      FeCl₃          :            HCl

                       2                :              6

                      20               :          6/2 ×20 = 60

                      H₂S             :          Fe₂S₃

                       3                :            1

                      15               :          1/3 ×15 = 5

                      H₂S            :            HCl

                       3                :              6

                      15                :          6/3 ×15 = 30

Hydrosulfuric acid producing less number of moles of product thus, it will act as limiting reactant.

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.