Is nuclear fission necessary in order to trigger a nuclear fusion reaction?

No, a fission reaction is not necessary to trigger a fusion reaction, but for us on earth, it is. In the field of nuclear weapons, a fission bomb is needed to create the heat necessary to set off a fusion weapon. We have to use fission, or, rather, the energy created by that, to initiate the fusion reaction. It might be possible to use a high power source, like a laser, on a small amount of material to get fusion to occur. But we are still experimenting with this in the Tokamak, and it's far from being a done deal. Stars are, in general, massive nuclear fusion reactors. Their constant consumption of fuel powering their high rate of fusion creates a massive amount of energy, and the stars' huge gravity keeps this process from blowing the whole thing apart. No fission is needed to sustain this reaction.

Exothermic,  physical change after it is already baked