A rigid cylinder with

a non redox reaction occurs when there is not a transfer of electrons. for redox reactions, which are reduction-oxidation reactions, a change in the oxidation number occurs. elements that are reduced gain electrons, and elements that are oxidized lose electrons.

explanation:

a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.