Chemistry, 24.11.2020 03:20 alexismurcia550

which two of these heats of reaction would be easiest and safest measure in the laboratory in which two are better obtain through reference sources? why?

which two of these heats of reaction would be easiest and safest measure in the laboratory in which

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Answerthis solution will not form a precipitateexplanationsolubility equilbrium: pbf₂(s) ⇄ pb²⁺(aq) + 2 f⁻(aq)the solubility product expression is $k_{sp} = [\text{pb}^{2+}][\text{f}^- ]^2 = 4 \times 10^{-8}$ (we exclude solids from the equilibrium expression).now suppose we have the trial ion product q, which we can define as $q = [\text{pb}^{2+}]_{\text{initial}} \cdot [\text{f}^- ]^2_{\text{initial}}$ then, we can interpret q as the product of the concentration of the ions that we have and ksp as the product of the ion concentrations that are needed to form a saturated solution.if q > ksp, then that implies that there will be a surplus of ions that exceed the amount that is required to form a saturated solution. a precipitate will then form (the precipitate continually forms until the surplus ions are removed and q is decreased to ksp's value).if q = ksp, the saturated solution that forms is barely saturated and the precipitate will be minimal.if q < ksp, then the ion concentration will not be enough to form a saturated solution (so no precipitate).using our information, we calculate the trial ion product: $\begin{aligned} q & = [\text{pb}^{2+}]_{\text{initial}} \cdot [\text{f}^- ]^2_{\text{initial}} \\ & = (1.9 \times 10^{-3} ) (3.8\times 10^{3})^2 \\ & = 2.7 \times 10^{-8} \end{aligned}$ since q = 2.7 × 10⁻⁸ < ksp = 4 × 10⁻⁸, a precipitate will not form.

Answer from: Quest

Answer charle's law

Answer from: Quest

answer is: empirical formula is tl₂o. if we use 100 grams of compound, tha:

m(tl) = 96.2% · 100 g ÷ 100%.

m(tl) = 96.2 g.

n(tl) = m(tl) ÷ m(tl). n(tl) = 96.2 g ÷ 204.4 g/mol.

n(tl) = 0.47 mol. m(o) = 3.77 g. n(o) = m(o) ÷ m(o). n(o) = 3.77 g ÷ 16 g/mol. n(ag) = 0.235 mol. n(tl) . n(o) = 0.47 mol : 0.235 mol /0.235. n(tl) . n(o) = 2 : 1.

m(tl₂o) = 204.4 g/mol · 2 + 16 g/mol = 424.8 g/mol.

m(compound) = 456. 8 g/mol - 424.8 g/mol = 32 g/mol ( 2 oxygens); tl₂o₃.

Answer from: Quest

Reaction involved in present system is : c12h22o11 + h2o → 2 c6h12o6the reaction system is obeying following rate law: rate = k[c12h22o11]thus, it is a first order reaction.now, for 1st order reactionrate constant (k) = $\frac{2.303}{t} log \frac{\text{initial conc.}}{\text{final conc.}}$ given: initial conc. = 3.0 g, final conc. = 2.7 g, t = 2.5 h∴rate constant (k) = $\frac{2.303}{2.5} log \frac{\text{3.0}}{\text{2.7}}$ ∴ k = 0.04215 h-1now, for 1st order reaction, half life = 0.693/k = 0.693/0.04215 = 16.4 hthus correct answer is option b

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