Can anyone explain me why the electron configuration of the vanadium atom is [Ar] 3d34s2 not [Ar] 4s23d3?

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

the positions which points up in upward carbon and down in downward carbon are axial

and vice versa holds true for equatorial positions

so the correct answer with labelled diagram will be

a. the law of proportion states the combination of 2 atoms in a specific ratio to produce multiple compounds such as the given statement of question ‘1st compound contains 88.8 % cu ’ indicates 88.8 g of cu is present along with 11.2 g oxygen in 100 g of compound whereas the statement ‘2st compound contains 79.9 % cu ’ indicates 79.9 g of cu is present along with 20.1 g oxygen in 100 g of compound

1st compound contains 88.8 g cu

for cu

m = 63 g /mol

atomic % = 88.8 /63 = 1.42

for o

m = 16 g /mol

atomic % = 11.2 /16 = 0.7

b. the emperical formula of 1st compound is

cu1.4o0.7

cu2o