PLEASE PLEASE HELP CHEMISTRY!! 15 POINTS

The boiling point of liquids is very high what does it indicate

If i initially have a gas at a pressure of 12 atm, a volume of 23 liters, and a temperature of 200 k, and then i raise the pressure to 14 atm and increase the temperature to 300 k, what is the new volume of the gas?

Look at the spectrums of a star moving towards earth and a motionless star. which of these is a correct inference that can be draw from the observation of the two spectrums? (2 points) the spectrum of a motionless star is difficult to be viewed separately using oridinary telescopes. the spectrum of a motionless star is identical to the spectrum of a star which moves towards earth. the spectrum of a star shifts towards the red region when the star moves towards earth. the spectrum of a star shifts towards the blue region when the star moves towards earth.